Optimal plasticisers

Elastomer to oil compatibility is the key to selecting plasticisers for rubber formulations. A major evaluation of mineral oils highlights the importance of polarity, and explains how Nynas is able to offer broad solutions.

Patrik Salomonsson

Development Engineer
Nynas AB

“Compatibility between the oil and the polymer is important, as it ensures proper miscibility of formulation components and long-term stability of the final rubber material,” says Patrik Salomonsson, Development Engineer, Nynas Naphthenics.

Oils are used by, for instance, tyre manufacturers to plasticise or soften commonly-used rigid polymers of high molecular weight, making these easier to process. By helping to solubilise and disperse various additives and fillers used in the compound formulation, the extender oils also play a part in modulating the rubber’s final physical properties, such as hardness, mechanical strength and durability. Furthermore, the intrinsic properties of the oil will influence the low temperature performance of the rubber.

A common method for assessing the compatibility between plasticisers and polymers is to immerse standard reference elastomers in oils under specific conditions, and then measure how the rubber pieces change in terms of mass and dimensions.

“Swelling or shrinkage, together with changes in hardness and other properties, will give you a good indication of the mutual affinity between the components,” explains Patrik Salomonsson.

Evaluating Nynas process oils with a broad range of elastomers of varying type, composition and curing chemistries, covering the entire spectrum from non-polar to highly polar elastomers, he was able to establish the advantages of naphthenic oils.

“Generally speaking, mineral oils exhibit low polarity due to their non-polar paraffinic chains. Any addition to the polarity will depend on the degree of unsaturation, usually in the form of aromatic structures. Owing to its high content of naphthenic rings, which are an intermediary between paraffinic and aromatic molecules in terms of solvent power, the polarity of naphthenic oils can be optimised to produce plasticisers with a balanced or even customised paraffinic, naphthenic or aromatic character,” he says.

“It is the versatility of naphthenic oils that enables Nynas to offer solutions to a wide range of rubber producers.”

Polarity match

  • The comprehensive study showed that matching polarity is key to successful compatibility between oil and polymer. In naphthenic oils, the polarity can be optimised, enabling it to match the polarity of the polymer used in a particular rubber formulation.
  • The results also indicate how a plasticiser’s average molecular weight, viscosity gravity constant and aniline point – the latter two being common solvency indicators – can be used to predict process oil compatibility with various elastomers.

Further reading

Assisting an agent

Compatible with all sorts of rubber, naphthenic oil facilitates the dispersion of insoluble sulfur, the vulcanising agent used in the production of tyre rubber. Anna Eriksson explains how this helps improve the quality of the final rubber.

A winning recipe for winter tyres

Offering excellent low temperature performance as winter tyre plasticisers, Nynas NYTEX® oils, including the new bio-based tyre oil NYTEX® BIO 6200, prove perfect for a growing, but demanding market.

Good vibes for antivibration

Antivibration rubber made with naphthenic process oils showed promising results in a comparative study conducted at Nynas Rubber Compounding Lab.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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General Manager Germany & Austria

Lars Fischer

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Sales Executive Process Oils

 Elena Campmann

Elena Campmann

Customer Service Specialist – Global Processes and Development Lead

Selina Walther

Selina Walther

Customer Service Coordinator

Michelle Krämer

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Customer Service Coordinator

David Barnett

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General Manager

 Samantha Moodley

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Customer Service Executive

Lee Anne Williams

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Customer Service Coordinator

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Global Customer Service Specialist & Project lead

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Global Customer Service Specialist & Project lead

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Sales Manager

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Customer Service Coordinator

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Global Customer Service Specialist & Project lead

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Customer Service Executive

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Customer Service Coordinator

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Sales Manager

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Customer Service Coordinator

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Global Customer Service Specialist & Project lead

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Customer Service Executive

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Customer Service Coordinator

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Customer Service Executive

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Customer Service Executive

Alistair Meyer

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Regional Director

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Area Sales Manager

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Regional Director

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Sales Manager

Shoeb Ahmed

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Customer Service Coordinator

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Global Customer Service Specialist & Project lead

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Marcela Tocelis

Sales Manager / Acting General Manager

David Barnett

David Barnett

General Manager

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Customer Service Executive

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Customer Service Coordinator

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Sales Manager

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Sales Executive Nordic

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Customer Service Coordinator

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Sales Manager France

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Customer Service Executive

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Customer Service Coordinator

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Customer Service Coordinator

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Sales Manager

Shoeb Ahmed

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Customer Service Coordinator

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Global Customer Service Specialist & Project lead

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

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Sales Manager France

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Customer Service Executive

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Customer Service Coordinator

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Customer Service Executive

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Lee Anne Williams

Customer Service Coordinator

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Sameen Kadli

Sales Manager

Shoeb Ahmed

Shoeb Ahmed

Customer Service Coordinator

 Sibala Libish Kumar

Sibala Libish Kumar

Global Customer Service Specialist & Project lead

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator