Hot solution for hot melts

By boosting the compatibility of ingredients, naphthenic mineral oils are providing hot melt adhesive manufacturers with new and more flexible formulations

By boosting the compatibility of ingredients, naphthenic mineral oils are providing hot melt adhesive manufacturers with new and more flexible formulations.

For producers of hot melt adhesives, using metallocene-based polyolefins and resins derived from natural resources can offer significant cost-advantages. Naturally derived resins are typically less expensive to use as a tackifier than alternative hydrocarbon resins, partly because their production is based on renewable feedstock.

The challenge for manufacturers lies in incorporating these ingredients - which are typically incompatible - into hot melt formulations. The catalyst metallocene is being hailed as revolutionary for the polymer industry, but natural resins are not compatible with metallocene polyolefins (mPOs), which are also much easier to manufacture than traditional polymers.

This is where Nynas oils offer a solution. Naphthenic mineral oils show great promise as enablers of compatible mixtures, paving the way for more flexible hot melt formulations and a reduced risk exposure to feedstock shortages.

Studies carried out by Nynas demonstrate that oil with a high degree of polarity shows superior performance. Naturally based resins are polar materials, and in hot melts, the resin is typically dissolved in the oil.

However, for final formulations including polymers, peel performance testing of hot melt formulations reveals that the polarity of the oil is not the only determining factor for compatibility between natural resins and mPOs.

Investigating mineral oil, natural resin and mPO hot melt formulations

Rheology and cloud point studies show the oil/resin and resin/polymer compatibility for a variety of tackifiers and oils with different characteristics.

In Figure 1, rheological data indicates how the oil is able to render typically incompatible blends compatible.

Figure 2 illustrates that although hydrocarbon resin formulations deliver improved overall peel strength, results are comparable. Some alternative resin formulations display an improved peel strength on glass and polyethylene surfaces.

Further reading

Fertile formulations

Having established in-house coating and testing of solid fertiliser, a Nynas researcher finds that naphthenic process oils offer coating formulations capable of reducing both dust and caking issues.

Naphthenic oil improves artificial fertilisers

The use of fertilisers around the world to boost agricultural production is both vital and constantly under critical scrutiny. Developing products that provide optimum benefits both economically and from an ecological viewpoint is an important challenge for the artificial fertiliser producer. Very small quantities of oil are employed in the production of fertilisers. The market demands optimal products and every link of the chain must be taken into consideration, including the properties of the oil being used.

Solving the puzzle of Solubility

Solubility is a key focus point for Nynas’ researchers as it is one of the main characteristics to consider when choosing process oil for different applications. However, as the established methods for measuring the dissolving capability of oil are not ideal, the researchers are looking for alternatives.

THERE IS MORE TO US THAN THIS

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